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  3. Midori Akiyama

Midori Akiyama

Assistant Professor, Graduate School of Engineering, Kyoto University *Profile is at the time of the award.

2023Inamori Research GrantsScience & Engineering

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Research topics
Development of Spatiotemporally Controlled Reaction Probes Based on Catalytic Function of Carbon–Carbon Double Bonds
Keyword
Summary
Perfluorocubane, in which fluorine atoms are introduced to all carbons of cubane, a box-shaped molecule, has been expected to "capture an electron inside". We recently succeeded in synthesis of this molecule for the first time, and observed the electron trapped inside. Can an electron in this box be extracted? To answer this question, we will study the electronic conductivity of perfluorocubane.

Comment

I want to bring out the best in my lovely child (molecule).

Outline of Research Achievments

We evaluated the single-molecule conductance of perfluorinated cubane derivatives versus non-fluorinated references via the STM-BJ technique. During this study, we established a synthesis for hexafluorodihalocubanes. Structural analysis of the iodine derivative revealed the shortest C(sp3)–I bond recorded to date, the origins of which were clarified using theoretical chemistry.


Masafumi Sugiyama et al. (2024) Exceptionally Short Tetracoordinated Carbon−Halogen Bonds in Hexafluorodihalocubanes Journal of the American Chemical Society 146 (44) doi:10.1021/jacs.4c12732


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